The main objective of this work is to optimize the synthesis of a novel TPMA-based chiral supramolecular cage complexed with Cu(II) and exploit it in electrochemically activated atom transfer radical polymerization (eATRP). In particular, we will try to develop stereoselective radical reactions taking advantage of chiral confined cages and to reveal potential and limitations in the exploitation of active metal sites embedded in a confined space synergically exploiting the recognition properties peculiar of nanospaces.

The main objective of this work is to optimize the synthesis of a novel TPMA-based chiral supramolecular cage complexed with Cu(II) and exploit it in electrochemically activated atom transfer radical polymerization (eATRP). In particular, we will try to develop stereoselective radical reactions taking advantage of chiral confined cages and to reveal potential and limitations in the exploitation of active metal sites embedded in a confined space synergically exploiting the recognition properties peculiar of nanospaces.

Polymerisation Catalysis in Confined Spaces

ZUPPARDO, GRETA
2021/2022

Abstract

The main objective of this work is to optimize the synthesis of a novel TPMA-based chiral supramolecular cage complexed with Cu(II) and exploit it in electrochemically activated atom transfer radical polymerization (eATRP). In particular, we will try to develop stereoselective radical reactions taking advantage of chiral confined cages and to reveal potential and limitations in the exploitation of active metal sites embedded in a confined space synergically exploiting the recognition properties peculiar of nanospaces.
2021
Polymerisation Catalysis in Confined Spaces
The main objective of this work is to optimize the synthesis of a novel TPMA-based chiral supramolecular cage complexed with Cu(II) and exploit it in electrochemically activated atom transfer radical polymerization (eATRP). In particular, we will try to develop stereoselective radical reactions taking advantage of chiral confined cages and to reveal potential and limitations in the exploitation of active metal sites embedded in a confined space synergically exploiting the recognition properties peculiar of nanospaces.
Supramolecular cages
Polymerisation
Catalysis
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.12608/34921