Synthesis of Hydrolitically-stable Molecular Cages via [3,3] Diaza-Cope Rearrangement

In recent years, Dynamic Covalent chemistry, in particular imine formation, has allowed to create increasingly complex supramolecular structures with well defined shapes and sized. Nonetheless, the lability of the imine bonds could limit the functional applicability of the resulting architectures. In this thesis, a novel methodolology based on diaza-cope rearrengement, has been employed to obtain novel hydrolitically stable organic cages.