The use of radicals as intermediates in total synthesis has evolved since their initial use in the latter half of the twentieth century. Radical generation from metal hydride methodologies has shifted to “greener” techniques including catalytic metal-mediated systems, electrochemical and photoredox-mediated processes. This thesis will focus on these classical and contemporary methods for radical generation and their applications in recent total syntheses.
Green synthetic methodologies for radical generation
CATALDI, FRANCESCO
2021/2022
Abstract
The use of radicals as intermediates in total synthesis has evolved since their initial use in the latter half of the twentieth century. Radical generation from metal hydride methodologies has shifted to “greener” techniques including catalytic metal-mediated systems, electrochemical and photoredox-mediated processes. This thesis will focus on these classical and contemporary methods for radical generation and their applications in recent total syntheses.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
GREEN SYNTHETIC METHODOLOGIES FOR RADICAL.pdf
accesso aperto
Dimensione
634.58 kB
Formato
Adobe PDF
|
634.58 kB | Adobe PDF | Visualizza/Apri |
The text of this website © Università degli studi di Padova. Full Text are published under a non-exclusive license. Metadata are under a CC0 License
Utilizza questo identificativo per citare o creare un link a questo documento:
https://hdl.handle.net/20.500.12608/11485